Abstract

The monolayers structure, orientation, and chemical interaction at metallic and nonmetallic substrates have been studied by infrared reflection spectroscopy. The reflection spectra of a thin film deposited on different substrates are generally modified by the optical effects as compared to the corresponding transmission spectra of the same film without a substrate support. Distinguishing the changes observed in reflection spectra caused by optical effects is crucial for the interpretation of the spectroscopic data and must be done before relating any differences in band shape, position, and intensity to structural and /or chemical bonding changes in the thin film

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