Abstract
Using a competitive spin-trapping method, we determined the effect of high static pressure on the trapping rate of hydroxyl and phenyl radical in solution. Under various pressures, hydroxyl or phenyl radicals were produced in solution in the presence of two different spin-trapping compounds, and the yield of trapped products was used to calculate relative trapping rates. We found that external pressure increases the phenyl-radical trapping rates by approximately 40% at the pressure of 490 bar, while there was no pressure effect in hydroxyl-radical trapping rates. We interpreted the pressure effect based on the reactivity difference of phenyl and hydroxyl radicals to the spin trap which is mainly caused by the variation in the volume of the group.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
