Extensional Flow-Induced Concentration Gradient in Entangled Polymer Solutions with Chemically Identical Species.

Abstract

Entangled polymer solutions show different rheological behavior from melts in fast extensional flow. This discrepancy is not expected according to the classic tube model and is an urgent issue to be solved in polymer physics. While in the tube model the polymer concentration is considered to be homogeneous, we show that extensional flow-induced concentration gradient may happen in polymer solutions even with chemically identical solutes and solvents. Through labeling an aggregation-induced emission (AIE) probe on oligomeric solvents, the flow-induced concentration gradient is visualized by combining extensional rheology and ex situ fluorescence microscopy. Microdomains of oligomeric solvents with a length scale of tens of micrometers are observed, and their influence on rheological behavior cannot be ignored.