Abstract
A computational code based on the method of continued fractions, previouslydeveloped by our group for electron–molecule scattering calculations, isextended to treat photoionization of molecules of arbitrary symmetry. Thisnew computational code is applied to study the photoionization of thetwo outermost valence orbitals of ammonia in the exact static-exchangelevel of approximation. The method has proved to be very accurate andrapidly convergent. Our results obtained for cross sections agree well withboth experimental and theoretical results available in the literature.
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More From: Journal of Physics B: Atomic, Molecular and Optical Physics
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