Abstract
Shariat M.H., Dehghany F. and Moshfeghian M., 1993. Extension and evaluation of the chain-of-rotator group contribution equation of state for prediction of thermodynamic properties of polar and non-polar compounds. Fluid Phase Equilibria, 85: 19-40. In this paper, the parameters for the chain-of-rotator group contribution ( CORGC) equation of state, which were recently reported by Pults et al. (Pults J.D., Greenkorn R.A. and Chao K.C., 1989. Chem. Eng. Sci., 44 (II): 2553-2564), have been revised. In addition, the ability of this equation to predict PVT properties of polar compounds and refrigerants is evaluated. For this reason parameters of the CORGC equation of state for these kinds of groups were obtained. Its ability to handle vapour-liquid equilibria calculations was also tested. The interaction parameters for unlike pairs of groups have also been determined. Comparisons between the predicted results and the experimental data for several pure fluids and their mixtures are presented. The accuracy and capability of CORGC with these new sets of parameters are also compared with other widely used equations of state.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
