Abstract
The Born-Green equation was tested using molecular dynamics data for liquid rubidium at 319 K. The unsatisfactory results of this equation for the pair potential are caused by the insufficient precision of the Kirkwood approximation for describing the triplet correlation function g 3( r,s,t). A more realistic ansatz for g 3( r,s,t) was employed in the formulation of an extended Born-Green equation. This new approach gives much better results for the potential than the simple Born-Green equation.
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