Abstract
Eleven new bis-aryldithiolene nickel complexes have been synthesised to examine their electronic absorbance properties. They include a new type of chromophore based upon extended bis-aryldithiolene nickel complexes incorporating either 1,2,4,5-tetrathiolbenzene, 1,2,4,5-tetrathiol-3,6-dichloro-benzene or 1,2,4,5-tetrathiol-3,6-difluorobenzene as a ligand. The new complexes based upon the tetrathiol ligand possessed broad near infrared absorbance at energies lower than those of previously reported metal dithiolenes.
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