Abstract
Abstract Helium (He)-induced damage is a sensitive concern for the performance of tungsten plasma facing materials (W-PFMs). Recent experiments have revealed that trace impurities in He plasma can effectively prevent the formation of He bubbles and fuzz on W surfaces. To explore its plausibility and underlying mechanism, we performed a multiscale computational study that combines density functional theory calculations and object kinetic Monte Carlo simulations to investigate the effects of a small quantity of beryllium (Be) on the evolution of He bubbles. It is found that there is a strong attractive interaction between He and Be, which can be attributed to the decrease in electron density and the lattice distortion induced by embedded Be atoms. Therefore, the co-implantation of Be continuously introduces trapping centers for He. Due to the low implantation depth and high migration energy of Be, the Be atoms are located close to the surface, leading to the trapping of the majority of He within the near-surface region and the development of a shielding layer for He permeation. The presence of Be facilitates the dispersion of the trapped He, skewing the He clusters into smaller sizes. More importantly, the Be trapping centers bring the He clusters closer to the surface, significantly increasing the probability of bubble bursting and the release of He back to the vacuum. This ultimately leads to a lower retention of He in the case of He + Be co-irradiation, compared with the case of He-only irradiation. Consequently, our findings elucidate the suppressive effect of a low flux of Be atoms on the growth of He bubbles, highlighting the need to focus on synergetic effects between plasma species.
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