Exploring Microstructure Variations and Hydrogen Storage Characteristics in TiVNbCrNi High-Entropy Alloys with Different Ni Incorporation

Abstract

In recent years, high-entropy alloys (HEAs), as a novel class of hydrogen storage materials, have been deemed highly promising due to their extensive compositional tunability and the unique high entropy effects. This study aims to enhance the comprehensive hydrogen storage performance of the TiVNbCr-based HEA by introducing Ni. The effects of Ni addition on the microstructural evolution of the alloy and its impact on activation properties, hydrogen absorption and desorption kinetics, thermodynamics, and cycling performance under the complex physicochemical environment of multiple principal elements was systematically investigated. The findings indicate that Ni addition shortens the activation incubation period of the alloy but more Ni reduces the intrinsic hydrogen absorption kinetics. In the Ti25V30Nb10Cr33Ni2 alloy, a high reversible hydrogen storage capacity of up to 2.2 wt% at room temperature was achieved, surpassing most of the currently reported body-centered cubic (BCC)-structured high-entropy hydrogen storage alloys. Furthermore, the influence of Ni on the alloy's hydrogen desorption kinetics and cycling hydrogenation performance was studied. Results from 110 cycles of testing reveal that the introduction of Ni-induced Laves phases can act to relax stress, thereby reducing strain accumulation during the hydrogen absorption and desorption cycling process. This could provide guidance for the design of high-entropy hydrogen storage alloys with extended cycling lifetimes.