Abstract
Magnetocaloric properties of {MnII2(imH)2(H2O)4 [NbIV(CN)8]·4H2O}n molecular magnet are reported. The coordination polymer crystallizes in the monoclinic P21/c space group and displays a magnetic second-order phase transition at Tc ≈ 24.1 K. The relaxation calorimetry measurements are analyzed in order to determine the temperature dependence of the magnetic entropy change ΔSM as well as the adiabatic temperature change ΔTad for an array of applied field changes ranging from 0 to 9 T. For μ0ΔH = 5 T the entropy change ΔSM attains the maximum value of 6.55 J K−1 mol−1 (9.5 J K−1 kg−1) at 25.5 K, while the corresponding maximum value of ΔTad amounts to 2.02 K at 25.1 K. The critical behavior of the isothermal entropy change is discussed. In particular, the analysis of the field dependence of ΔSM in terms of the power law implies that the studied compound belongs to the mean-field universality class.
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