Abstract

Black soil in northeast China is gradually degraded and soil organic matter (SOM) content decreases at a rate of 0.5% per year because of the long-term cultivation. SOM content can be obtained rapidly by visible and near-infrared (Vis–NIR) spectroscopy. It is critical to select appropriate preprocessing techniques for SOM content estimation through Vis–NIR spectroscopy. This study explored three categories of preprocessing techniques to improve the accuracy of SOM content estimation in black soil area, and a total of 496 ground samples were collected from the typical black soil area at 0–15 cm in Hai Lun City, Heilongjiang Province, northeast of China. Three categories of preprocessing include denoising, data transformation and dimensionality reduction. For denoising, Svitzky-Golay filter (SGF), wavelet packet transform (WPT), multiplicative scatter correction (MSC), and none (N) were applied to spectrum of ground samples. For data transformation, fractional derivatives were allowed to vary from 0 to 2 with an increment of 0.2 at each step. For dimensionality reduction, multidimensional scaling (MDS) and locally linear embedding (LLE) were introduced and compared with principal component analysis (PCA), which was commonly used for dimensionality reduction of soil spectrum. After spectral pretreatments, a total of 132 partial least squares regression (PLSR) models were constructed for SOM content estimation. Results showed that SGF performed better than the other three denoising methods. Low-order derivatives can accentuate spectral features of soil for SOM content estimation; as the order increases from 0.8, the spectrum were more susceptible to spectral noise interferences. In most cases, 0.2–0.8 order derivatives exhibited the best estimation performance. Furthermore, PCA yielded the optimal predictability, the mean residual predictive deviation (RPD) and maximum RPD of the models using PCA were 1.79 and 2.60, respectively. The application of appropriate preprocessing techniques could improve the efficiency and accuracy of SOM content estimation, which is important for the protection of ecological and agricultural environment in black soil area.

Highlights

  • Soil organic matter (SOM) is one of the major factors for soil quality [1], and it affects soil physical structure, but is significant for ecosystem service, ecological environment, sustainable development of agriculture [2,3,4,5]

  • The spectral data of 496 soil samples was preprocessed in three parts: denoising, fractional derivatives and dimensionality reduction, and partial least squares regression (PLSR) was used for modeling

  • Compared with multiplicative scatter correction (MSC) and wavelet packet transform (WPT), Svitzky-Golay filter (SGF) can enhance the correlation between soil spectrum and SOM content more effectively

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Summary

Introduction

Soil organic matter (SOM) is one of the major factors for soil quality [1], and it affects soil physical structure, but is significant for ecosystem service, ecological environment, sustainable development of agriculture [2,3,4,5]. It is important to obtain the content of SOM in black soil area rapidly and accurately, in order to protect the ecological and agricultural environment in black soil area. Conventional SOM content estimation methods depend on chemical analysis of ground samples [9]. These methods perform well, they are time consuming and costly [10,11]. Researchers found visible and near-infrared spectrum is appropriate for SOM content estimation in spectrum of ground samples [13]. Visible and near-infrared (Vis-NIR) spectroscopy has been used as a cheap and fast remote sensing technology to estimate the SOM content [13]. Spectral preprocessing techniques are applied to remove the effects, such as baseline shift, light scattering, and to accentuate spectral features

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