Abstract
We report the two-step synthesis of a heterobimetallic oxamato-based metal-organic framework (MOF). First, we prepared an oxamato functionalized carbazole-based dinuclear copper(II) complex, K4{Cu2(carbox)2]}·8H2O, where the carbozale linkers exhibited an uncommon substitution pattern, carbox = N,N’-1,6-carbazolebis(oxamate). Then, this building block was used as a metalloligand toward manganese(II) metal ions to assemble a neutral three-dimensional (3 D) MOF with formula [Mn2Cu2(carbox)2(H2O)4]·6CH3OH·2H2O (1) and single-crystal X-ray diffraction determined the structure. The resulting network constitutes one of the few examples of oxamato-based 3 D MOF.
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