Abstract

Disentangled ultrahigh molecular weight polyethylene (UHMWPE) is a very promising material with extremely high tenacity and modulus. In this work, the effect of drawing on the morphological, physical, and mechanical properties of disentangled UHMWPE tapes was studied. The tapes were characterised by using the density gradient column method , wide-angle X-ray diffraction (WAXD), differential scanning calorimetry (DSC), polarised optical microscopy and scanning electron microscopy (SEM). The density and crystallinity of tape improved after each stage of drawing. The unoriented crystalline structure of the as-prepared UHMWPE tape gradually transformed into an oriented crystalline structure on drawing as confirmed by WAXD patterns. As the draw ratio increased, concomitant increase in birefringence, and tensile properties were also noticed. The tape obtained after the final stage of drawing had tensile properties similar to that of gel spun UHMWPE fibres. Hence, this tape was used to make prototype of soft armour panel (SAP) that stopped all the bullets fired when subjected to ballistic test and yielded very low back face signature (BFS) justifying the potential of disentangled UHMWPE tape as a ballistic material.

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