Experimental vs. Theoretical Viscosity Determination of Aluminosilicate Glasses.

Abstract

The paper presents the results of studies on the viscosity of the glass mass in various temperature ranges, determining the basic technological parameter, very important from the point of view of melting and forming. For this purpose, six sets based on natural raw materials such as basalt, dolomite, and amphibolite, modified with different amounts of float glass cullet, were melted. The melting process was carried out in an electric furnace at the temperature of 1450 °C for 2 h. Using the dilatometric method, high-temperature microscopy and theoretical calculation methods, the viscosity of the produced glasses was determined in various temperature ranges. Comparative analyses of the employed methods were carried out. The significance of the applied calculation methods for aluminosilicate glasses depending on the basic chemical composition of the glasses was presented. The relationship between the manner of incorporating amphoteric ions Al3+, Fe3+ and Mg2+ into the glass structure and the change in viscosity in the temperature range corresponding to the working point range at 104 [dPa·s] viscosity and the relaxation range-Tg temperature at 1013 [dPa·s] viscosity was justified. It was justified that in order to plot the viscosity curve with the correct slope in the forming range for aluminosilicate glasses, it is appropriate to use the two-point method based on the fixed viscosity points of 104 [dPa·s] and 1013 [dPa·s].