Abstract
Analysis of experimental results reveals that, in general, reactions of excess electrons in aqueous systems followed at the time scales electron spectral relaxations, or at shorter time scales, are dispersive while reactions followed at longer time scales than those of spectral relaxations are classical. In the latter case the internal rearrangements in the system have to be enough effective to preserve the distribution in electron reactivity during the course of reactions and because of this the classical kinetics is valid. The effects of system dynamics on kinetics of excess electrons are rationalized in terms of the renewal theory with a fractal set of renewal moments.
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