Abstract
In order to improve the soundness of the kinetic analysis of solid-state reactions, we present an experimental test based on a sudden change (jump), during an experiment, of the temperature, or of the partial pressure of gases, which have an influence on the kinetic rate. This test, denoted “ f( α) test” allows to discriminate if the kinetic modelling may or may not involve the rate equation d α/d t = kf( α) for any kind of reaction: thermal decomposition, solids reacting with gases, … Numerous examples are given and discussed according to the answer of the test, mainly based on the consideration of nucleation and growth processes.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
