Experimental study on the nitrogen dioxide and particulate matter emissions from diesel engine retrofitted with particulate oxidation catalyst

Abstract

A particulate oxidation catalyst (POC) was employed to perform experiments on the engine test bench to evaluate the effects on the nitrogen dioxide (NO2) and particulate matter (PM) emissions from diesel engine. The engine exhaust was sampled from both upstream and downstream of the POC. The results showed that the POC increased the ratios of NO2/NOx significantly in the middle and high loads, the ratio of NO2/nitrogen oxides (NOx) increased 4.5 times on average under all experiment modes with the POC. An engine exhaust particle sizer (EEPS) was used to study the particle number-weighted size distributions and the abnormal particle emissions with the POC. The results indicated that the average reduction rate of particle number (PN) was 61% in the operating range of the diesel engine. At the engine speed of 1400r/min, the reduction rates of PN tended to decrease with the larger particle size. In the long time run under the steady mode (520Nm, 1200r/min), abnormal particle emissions after the POC happened seven times in the first hour, and the average PN concentration of these abnormal emission peaks was much higher than that in normal state. The particle emissions of peaks 1–5 equaled the particles emitted downstream of the POC in normal state for 1.9h in number concentration, and for 3.6h in mass concentration. The PN concentrations tended to increase over time in 5h under the steady engine mode and the increase of the PN in the size range of 6.04–14.3nm was more evident.