Experimental study on the influence of brine concentration on the dissociation characteristics of methane hydrate

Abstract

Brine stimulation is a common method for assisting depressurization to produce hydrate, which significantly improves the efficiency of hydrate production. In this work, to study the influence of brine concentration on the natural gas hydrate production process, a novel cylindrical hydrate production simulation experimental device was established, and investigations of hydrate dissociation experiments induced by depressurization in conjunction with brine injection were carried out. The effects of different brine concentrations on the gas production rate and heat transfer during production were studied. The distribution, flow, and concentration evolution of brine during hydrate production were analyzed. Brine injection can significantly enhance cumulative gas production during the depressurization stage, increase the sensible heat for hydrate dissociation, enhance heat transfer between the hydrate reservoir and the environment during the recovery process, and significantly improve the gas production rate of hydrate. The increase in the gas production rate caused by brine injection mainly occurs at the end of the depressurization stage and the beginning of the constant pressure stage. The injected brine is mainly located in the middle and upper areas of the reactor. In the bottom area of the reactor, the hydrate has higher saturation and longer dissociation time, which is slightly affected by the injected brine. A higher hydrate saturation is not beneficial to brine injection and does not promote hydrate dissociation. Additionally, in the experiments with brine injection, the resistance decreases more obviously during the depressurization stage due to more hydrate dissociation. The resistance also shows that in the bottom area of the reactor, there is a higher hydrate saturation and a lower brine effect on hydrate.