Experimental study on the dynamic strength characteristics of combined heavy metals contaminated soil with nZVI treatment

Abstract

Nanoscale zero-valent iron (nZVI), a high-performance nanomaterial, can treat heavy metal contaminants and is extensively employed for in-situ treatment of groundwater and contaminated subsoil. However, there are few studies that indicate trends in the dynamic strength parameters of nZVI-treated soils to assess site safety. In this study, three heavy metal contaminants, Zn(II), Pb(II), and Ni(II), were selected to contaminate virgin soil. The heavy-metal-contaminated soil was treated with nZVI at two concentrations (a low dose and high dose of 0.5% and 2%, respectively) of the soil's dry mass. Analyses of particle size distribution revealed a consistent shift towards larger particles upon nZVI treatment, and the percentage of sand gradually increased. Heavy metal contamination decreased the liquid and plastic limits of the virgin soil, while those of the treated soil increased with nZVI content. The dynamic triaxial results showed significantly lower maximum dynamic shear modulus for MS, MS-LdN, and MS-HdN than for NS. The damping ratios of all samples showed an S-shaped trend. Thus, nZVI has the potential to create cemented structures and immobilize heavy metals. However, its effectiveness is significantly modulated by the initial water content of the soil. While the application of nZVI proves beneficial in immobilizing heavy metal contaminants, careful consideration is imperative under dynamic loading conditions.