Experimental study on pore structures and mechanical properties of ferroaluminate cement under sulfate attack

Abstract

Ferroaluminate cement (FAC) emerges as a special cement with outstanding durability, offering promising applications. However, the resistance to sulfate attack of FAC remains inadequately understood. In this paper, the impact of sulfate attack on the pore structure of FAC concrete is explored through nuclear magnetic resonance (NMR) tests from a microscopic perspective. Meanwhile, the macroscopic mechanical characteristics of concrete attacked by sulfate are investigated under different loading conditions, including splitting tensile and conventional triaxial compression. NMR test analysis shows that as the degree of erosion increases, the number of mesopores and macropores in FAC concrete decreases while the number of micropores increases. The changes in pore structure distribution alter the mechanical response of specimens. The discussion of strength characteristics, deformation behavior, and energy parameters in conventional triaxial tests reveals that FAC concrete attacked by sulfate exhibits superior mechanical properties under confining pressure. Uniaxial strength results indicate that sulfate attack has less impact on specimens under tensile stress state than under compression. Based on the experimental findings, this paper introduces a sulfate attack impact factor to capture the uniaxial strength changes. Further, a multiaxial strength criterion is developed to describe the strength properties of sulfate-attacked concrete under triaxial stress conditions.