Experimental Study on Microwave Drying Aluminum Hydroxide

Abstract

The aluminum hydroxide produced by the Bayer process contains a large amount of water which leads to the consumption of a large amount of heat for moisture removal in the calcination process, resulting in an increased energy consumption. The effects of temperature and microwave power on the dehydration ratio and the dry matter ratio of aluminum hydroxide were investigated. The characteristics of temperature variation during drying were discussed. X-ray diffraction (XRD), scanning electron microscopy (SEM), laser particle size, Fourier transform infrared (FTIR) spectroscopy, and dielectric property analyses were made to characterize the dried materials. The analysis results showed that within the range of bench-scale experimental parameters, the dehydration ratio was higher and the proportion of dry matter was lower at a higher final temperature. Within the range of pilot-scale experimental parameters, the dehydration ratio increased with the increasing microwave power from 500 W to 1500 W. XRD spectra revealed that when the final temperature exceeded 220 °C, a part of the aluminum hydroxide underwent a low-temperature phase transition to boehmite. The SEM images and a particle size analysis showed that there was no significant difference between the morphologies of the powder obtained by microwave drying and conventional drying methods. The powder obtained by both processes had an average particle size of around 80 μm. The dielectric constant and the dielectric loss of the dried material decreased greatly.