Abstract
Bioethanol as the renewable biomass fuel gradually becomes a promising feedstock for hydrogen production. To improve the efficiency of hydrogen production, a typical double-layer porous media burner was established for the partial oxidation reaction of ethanol (POE). The effects of porous media structure, initial ethanol and air conditions on the temperature distribution and gas production were investigated based on the start-up characteristics of the burner. The results indicate that the lowest start-up time (2400 s) and best hydrogen production (9.80%) were obtained by filling the downstream section with 8 mm Al2O3 pellets and introducing ethanol at the upstream inlet, compared with that of 6 and 10 mm pellets. The productions of methane and hydrogen were improved to some extent by adding the water with 10% fraction. And the highest concentration of hydrogen was achieved at the air velocity of 8 cm/s. When the O2/C ratios were 0.2 and 0.25, the maximum hydrogen yield (23.28%) and ethanol conversion (77.42%) were obtained respectively.
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