Abstract

Summary A significant amount of associated gas has been produced from shale oil reservoirs in the Ordos Basin, northern China, in recent years, which has provided an opportunity for using low-cost, associated gas in enhanced oil recovery (EOR) projects. However, there are few other reports of EOR projects in shale oil reservoirs using associated gas, and a quantitative evaluation of the technique is needed. Therefore, we conducted associated gas and waterflooding experiments in shale oil samples at constant and gradually increasing injection pressure while monitoring the spatial distribution of movable and residual oil by means of nuclear magnetic resonance (NMR) technology. Before the injection experiments, we performed mercury intrusion tests and measured the NMR transverse relaxation time, T2, of fully saturated samples to characterize the pore-throat size distribution of rock samples. Furthermore, we established a novel and robust mathematical model based on a fractal description of the pore space and a capillary tube model to determine the lower limit of the pore radius of movable oil, rc, during gas- and waterflooding. We observed that the oil recovery factor at a low injection pressure (i.e., 0.6 MPa) during the associated gasflooding was lower than that during waterflooding under both constant pressure injection mode and gradually increasing pressure injection mode. However, the performance of associated gasflooding was greatly improved by increasing the injection pressure. High injection pressure indeed produced a higher oil recovery factor, thinner residual oil film thickness, and smaller rc during associated gasflooding than during waterflooding under both injection modes. These differences in behavior appear to be linked to dissimilarities in flooding mechanisms at high and low injection pressures. Our main conclusion is that associated gasflooding at high injection pressure (i.e., 6 MPa) has a better potential for enhancing the oil recovery factor than waterflooding in shale oil reservoirs.

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