Experimental study of traveling waves in nonadiabatic fixed bed reactors for the oxidation of carbon monoxide

Abstract

An experimental study of axial temperature profiles in a nonadiabatic tubular fixed bed reactor has been made under the transient operation. The catalytic carbon monoxide oxidation occuring on a Pt/alumina catalyst has been used. Unlike the adiabatic conditions the velocity of a traveling temperature wave in a nonadiabatical arrangement depends on its axial position. In certain regions of inlet concentration multiple temperature fronts have been observed. For low inlet CO concentration a downstream temperature wave results and the lower (kinetic) steady state is dominant. For high inlet CO concentration an upstream propagating front results and the upper steady state is dominant. For a downstream moving wave oscillations of wave velocity, hot spot temperature and exit conversion have been measured. For certain operating conditions periodic behavior of temperature profiles in the reactor has been observed.