Abstract
When a tank experiences a boilover fire, oil droplets splash, heat release rate and flame height increase, posing significant hazards. Water is a necessary condition for boilover to occur, but current research mainly focuses on boilover caused by water layer, neglecting the influence of water content inherent in crude oil on boilover phenomena. In this study, crude oil with a water content ranging from 0.26 % to 3 % was utilized, and a series of boilover fire experiments were conducted by varying the presence or absence of a water layer and the initial oil thickness and by carrying out a series of boilover fire experiments focusing on the effect of water content on the boilover phenomenon. The results indicate that emulsified crude oil has a droplet micro-explosion phase during the stable combustion stage. When no water layer is present, the boilover process duration is brief, and the transient injection effect is notable, with boilover intensity increasing with water content. Upon adding a water layer, emulsified water abbreviates the boilover onset time, diminishes the combustion rate, and promotes the formation of the hot zone. The upper and lower limit values of the hot zone temperature decrease with increasing water content, while the temperature difference remains essentially unaffected, remaining constant at about 50 °C. Boilover intensity exhibits a nonlinear relationship with increasing water content, peaking at 2 % water content. The pre-boilover burned mass ratio remains relatively stable, maintained between 12 % and 15 % across all working conditions. Both the splash range and maximum heat flux increase with initial oil layer thickness but show no significant change with water content. Moreover, the safety distance corresponding to the heat radiation threshold exceeds the splash distance, indicating that heat radiation hazards predominate. The results of this paper will help provide guidance for fighting emulsified crude oil fires.
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