Experimental study of hydrogen production from reforming of methane and ammonia assisted by Laval nozzle arc discharge

Abstract

The production of hydrogen from hydrogen compounds for fuel cell or internal combustion engine applications is a potential method for responding to the energy crisis and environmental problems. In this work carbon dioxide reforming of methane and decomposition of ammonia using a Laval nozzle arc discharge (LNAD) reactor has been exploited at atmospheric pressure without external heating or catalysts. CH4 (or NH3) conversion and H2 selectivity were observed to be negatively correlated with the concentration of CH4 (or NH3) and the flux of CO2 (N2) and positively correlated with voltage and the Laval nozzle throat radius. Power consumption increased with the concentration of methane at the same CO2 flow rate, and the conversion of methane gradually increased with the content of water vapor in the gas mixture. A high conversion rate and fair H2 selectivity were achieved, 51% and 37.5%, respectively, when the methane and carbon dioxide flow rates were 4 L/min and 14 L/min, respectively, and the minimum distance between the two electrodes was 2.5 mm. The LNAD reactor used in this study exhibited a good conversion rate and low energy consumption, which should be suitable for the industrial scale-up of the system.