Experimental Study of Chemical-Looping Reforming in a Fixed-Bed Reactor: Performance Investigation of Different Oxygen Carriers on Al2O3 and TiO2 Support

Abstract

This study examines the hydrogen production by the steam reforming of methane integrated to chemical-looping reforming (CLR) as a novel technology in a fixed-bed reactor at 700–1200 °C. The particles are present in two consecutive oxidation and reduction steps. In the reduction step, the oxygen carrier is reduced with the fuel, which, in turn, is partially oxidized to H2 and CO (synthesis gas), and in the oxidation step, the reduced oxygen carrier is reoxidized with oxygen (O2 + argon). The oxygen carriers Fe, Mn, Co, and Cu using inert materials Al2O3 and TiO2 as a support are prepared by the precipitation method. The samples are analyzed using energy-dispersive X-ray analysis (EDX), scanning electron microscopy (SEM), and X-ray diffraction (XRD) to check the carrier specifications before and after the process. The main goal of this study is investigation of the reactivity of different metal oxides on Al2O3 and TiO2 support. The conversion of fuel into products depends upon the type of oxygen carriers an...