Abstract
The free radical reaction of C2Cl3 with NO2 was investigated by step-scan time-resolved FTIR (TR-FTIR) emission spectroscopy. Due to the vibrationally excited products of Cl2CO, NO, and CO, strong IR emission bands were observed with high resolution TR-FTIR spectra. Four reaction channels forming C2Cl3O+NO, CCl3CO+NO, CO+NO+CCl3, and ClCNO+Cl2CO were elucidated, respectively. Spectral fitting showed that the product CO was highly vibrationally excited with the nascent average vibrational energy of {60.2 kJ/mol}. Possible reaction mechanism via intermediates C2Cl3NO2 and C2Cl3ONO was proposed.
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