Experimental research on the cook-off energy release of Al/PTFE mixed powder in closed container

Abstract

AbstractTo evaluate the reactive energy release of the Al/Polytetrafluoroethylene (PTFE) mixed powder (Al and PTFE with a mass percentage of 26.5%/73.5%). Based on the traditional formula, three kinds of Al/PTFE test samples with different dosages (4, 6.5, and 9 g) were mixed. By using the self-designed airtight container, and combining with the overpressure sensor, the transient optical fiber pyrometer, and the infrared thermography. The overpressure , the visible light radiation temperature in the closed container, and the infrared light radiant temperature of the container’s outer wall have been obtained by real-time measurements during the process of cooking off, and the reaction products are analyzed by X-ray energy spectrum (EDS) and X- ray diffraction (XRD). The experimental results show that most of the solid products of Al/PTFE powder in the closed container are AlF3 and a small number of intermediate carbon compositions. The released energy during the firing process of the active material Al/PTFE increases with the increase of the mixing amount; The bake-off energy of active material Al/PTFE mixture per unit mass in a closed container is about 10.2 kJ/g, and when the oxygen content in the closed container is sufficient, active material Al/PTFE per unit mass releases more energy.