Experimental redetermination of the gas-phase enthalpy of formation of ethyl 2-thiophenecarboxylate

Abstract

The condensed phase standard (p°=0.1MPa) molar enthalpy of formation of ethyl-2-thiophenecarboxylate was derived from the remeasured standard molar energy of combustion, in oxygen, at T=298.15K, by rotating bomb combustion calorimetry and the standard molar enthalpy of vaporization, at T=298.15K, remeasured by Calvet microcalorimetry. Combining these two values, the following enthalpy of formation in the gas phase, at T=298.15K, was then derived for ethyl-2-thiophenecarboxylate: −(277.7±2.9)kJ·mol−1. The calculated gas-phase enthalpy of formation of the title compound, through the G3(MP2)//B3LYP approach was found to be 278.9kJ·mol−1, in excellent agreement with the experimental measured value.