Abstract
Phase equilibria of the binary PbO-ZnO and ternary PbO-ZnO-SiO2 systems have been experimentally investigated at 1033–1898 K (760–1625 °C) for oxide liquid in equilibrium with air and solid oxide phases: tridymite or cristobalite (SiO2), willemite (Zn2SiO4), zincite (ZnO), larsenite (PbZnSiO4) and lead-zinc melilite (Pb2ZnSi2O7) covering the ranges of concentrations not studied before. High-temperature equilibration on primary phase or inert metal (platinum) substrates, followed by quenching and direct measurement of the Pb, Zn and Si concentrations in the phases with the electron probe X-ray microanalysis (EPMA) has been used. Liquidus phase equilibrium data is essential for the development of the thermodynamic model.
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