Experimental investigation on NO emission and burnout characteristics of high-temperature char under the improved preheating combustion technology

Abstract

In order to avoid the formation of NO from the nitrogen-containing pyrolysis components in the main combustion zone under preheating combustion technology, an improved preheating combustion technology was proposed. A two-stage drop-tube furnace was built to study the NO emission and combustion characteristics of high-temperature char (HTC) under the improved preheating combustion technology. The char was first heated to the initial pyrolysis temperature(600℃,800℃ and 1000℃) in the upper furnace under the atmosphere of nitrogen, before being burned in the second furnace. The influence of important operating parameters such as HTC temperature(600℃,800℃ and 1000℃), combustion temperature (1200℃,1300℃ and 1400℃)and excess air ratio (0.6 ∼ 1.4)were analyzed. The results show that raising the HTC temperature helps to reduce NO emissions. The maximum NO reduction efficiency is 21.1 % when the excess air ratio(α) = 1.0, which differs from the reported literature results of room-temperature char (RTC). In HTC, there is no absolute correlation observed between the BET area and NO reduction. The release of C and N is altered by pre-ignition of char at HTC; additionally, the evolution of nitrogen functional groups during the pyrolysis process is more key influencing factors. The stoichiometric ratio has a considerable influence on the effects of combustion temperature on NO emission. When there is a lack of oxygen, NOx emissions decrease as the temperature rises, whereas under oxygen-rich situations the converse is true. With the increase in HTC temperature from 600 °C to 1000 °C, the critical excess air ratio steadily increases from 0.75 to 0.85. The carbon concentration of fly ash can be reduced by increasing both the HTC and the combustion temperature. The largest reduction in carbon content in fly ash is 28.6 % at α = 1.0.