Experimental investigation on dyeing wastewater treatment and by-product hydrogen with a reverse electrodialysis flocculator

Abstract

Hydrogen production and dye degradation can be achieved simultaneously in a hybrid system of reverse electrodialysis（RED）and electrocoagulation (EC), using current derived from the salinity gradient energy. Under the current, Fe electrode is used as the anode to produce Fe2+(subsequently oxidized to Fe3+) which combines with OH− produced from the cathode to remove the dyes, while the hydrogen gas produced by the cathode is collected by a hydrogen collection device. The experiments are carried out to investigate the effects of different initial concentrations, pH, currents, electrode rinse solution (ERS) flow rates and the addition of chlorine on the degradation rate and hydrogen production. The results indicate that the degradation rate and hydrogen production could reach 98.3% and 150 m h−1 at alkaline condition (pH = 11) and acidic condition (pH = 3) respectively, with a current of 0.4 A. The degradation rate and hydrogen production increase significantly with an increase in current.