Experimental Investigation of the Mechanisms of Salt Precipitation during CO2 Injection in Sandstone

Yen Adams Sokama-Neuyam,Patrick Boakye,Jann Rune Ursin

doi:10.3390/c5010004

Yen Adams Sokama-Neuyam, Patrick Boakye + Show 1 more

Open Access

https://doi.org/10.3390/c5010004

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Abstract

Deep saline reservoirs have the highest volumetric CO2 storage potential, but drying and salt precipitation during CO2 injection could severely impair CO2 injectivity. The physical mechanisms and impact of salt precipitation, especially in the injection area, is still not fully understood. Core-flood experiments were conducted to investigate the mechanisms of external and internal salt precipitation in sandstone rocks. CO2 Low Salinity Alternating Gas (CO2-LSWAG) injection as a potential mitigation technique to reduce injectivity impairment induced by salt precipitation was also studied. We found that poor sweep and high brine salinity could increase salt deposition on the surface of the injection area. The results also indicate that the amount of salt precipitated in the dry-out zone does not change significantly during the drying process, as large portion of the precipitated salt accumulate in the injection vicinity. However, the distribution of salt in the dry-out zone was found to change markedly when more CO2 was injected after salt precipitation. This suggests that CO2 injectivity impairment induced by salt precipitation is probably dynamic rather than a static process. It was also found that CO2-LSWAG could improve CO2 injectivity after salt precipitation. However, below a critical diluent brine salinity, CO2-LSWAG did not improve injectivity. These findings provide vital understanding of core-scale physical mechanisms of the impact of salt precipitation on CO2 injectivity in saline reservoirs. The insight gained could be implemented in simulation models to improve the quantification of injectivity losses during CO2 injection into saline sandstone reservoirs.

Highlights

CO2 Capture, Utilisation and Storage (CCUS) is a vital mitigation technique to meet the globalCO2 emission reduction target and prevent climate change [1,2]
We have examined the mechanisms of salt cake deposition on the surface of the injection inlet could abate external and internal salt precipitation by improving sweep efficiency at the injection inlet
The magnitude of CO2 injectivity impairment is dependent on both solid salt show that continuous injection of CO2 after salt precipitation could alter the distribution of solid salt saturation and the distribution of deposited salt within the pore spaces

Summary

Introduction

CO2 Capture, Utilisation and Storage (CCUS) is a vital mitigation technique to meet the globalCO2 emission reduction target and prevent climate change [1,2]. A threshold well injectivity and robust containment are prerequisites to a successful CCUS project. Deep saline reservoirs are readily accessible with high volumetric capacity to sequester large volumes of CO2 [3,4,5,6]. Drying and salt precipitation especially in the injection area could impair CO2 injectivity in deep saline reservoirs. Salt precipitation is a well-known flow impairment challenge in natural gas injection and production. Kleinitz et al [7] reported dramatic halite precipitation around the wellbore during production of natural gas. Similar field cases have been reported during injection, storage and production of gas [8,9,10]. In terms of field pilots, strong evidence of salt precipitation effects during CO2 injection

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