Experimental Investigation of Foam Flooding Using Anionic and Nonionic Surfactants: A Screening Scenario to Assess the Effects of Salinity and pH on Foam Stability and Foam Height.

Abstract

Gravity override and viscous fingering are inevitable in gas flooding for improving hydrocarbon production from petroleum reservoirs. Foam is used to regulate gas mobility and consequently improve sweep efficiency. In the enhanced oil recovery process, when the foam is introduced into the reservoir and exposed to the initial saline water saturation and pH condition, selection of the stable foam is crucial. Salinity and pH tolerance of generated foams are a unique concern in high salinity and pH variable reservoirs. NaOH and HCl are used for adjusting the pH, and NaCl and CaCl2 are utilized to change salinity. Through analyzing these two factors along with surfactant concentration, we have instituted a screening scenario to optimize the effects of salinity, pH, surfactant type, and concentration to generate the most stable state of the generated foams. An anionic (sodium dodecyl sulfate) and a nonionic (lauric alcohol ethoxylate-7) surfactants were utilized to investigate the effects of the surfactant type. The results were applied in a 40 cm synthetic porous media fully saturated with distilled water to illustrate their effects on water recovery at ambient conditions. This most stable foam along with eight different stabilities and foamabilities and air alone was injected into the sand pack. The results show that in optimum surfactant concentration, the stability of LA-7 was not highly changed with salinity alteration. Also, we probed that serious effects on foam stability are due to divalent salt and CaCl2. Finally, we found the most water recovery that was obtained by the three most stable foams by the formula of 1 cmc SDS + 0.5 M NaCl, 1 cmc SDS + 0.01 M CaCl2, and LA-7@ pH ∼ 6 from porous media flooding. Total water recovery for the most stable foam increased by an amount of 65% compared to the state of air alone. A good correlation between foam stability and foamability at higher foam stabilities was observed.