Experimental investigation of degradation mechanism in proton exchange membrane water electrolyzer under prolonged and severe bubble accumulation condition

Abstract

Proton exchange membrane water electrolyzer (PEMWE) exhibits significant potential as a technology for hydrogen production driven by sustainable energy sources. In this study, the performance degradation characteristics of PEMWE under severe bubble accumulation condition lasting 100 h were investigated through in-situ and ex-situ characterization techniques. The results show that an increasing performance disparity with higher voltage, notably at lower temperatures, reaching a 58.2 % current density degradation rate at 50 °C and 2.0 V. Electrochemical impedance spectroscopy (EIS) analysis suggests that electrolyzer performance degradation is mainly due to increased charge transfer impedance, especially at the anode. In addition, the degraded electrolyzer exhibits a significant delay in reaching a stable current density during the abrupt voltage loading process, and its Tafel slope and electrochemically active surface area (ECSA) increased and decreased by 12.8 % and 13.5 %, respectively. Based on scanning electron microscopy (SEM) images, post-experiment analysis reveals pronounced thinning and noticeable cracks in both cathode and anode catalyst layers near the outlet, particularly on the anode side. Additionally, energy dispersive spectroscopy (EDS) mappings and transmission electron microscopy (TEM) images confirm substantial Pt/C and IrO2 catalyst particle dissolution, migration, and agglomeration. The findings of this study contribute to enhancing understanding of the performance degradation mechanisms in PEMWE.