Experimental evaluation of lime spray drying for SO<sub>2</sub> absorption

Abstract

<abstract> <p>This paper presents the findings of an experimental investigation on the performance of a laboratory-scale spray dryer involving flue gas desulfurization. Using commercial hydrated lime as a sorbent, a systematic set of experiments were performed to evaluate SO<sub>2</sub> absorption capacity of the spray dryer. The experimentation involved accurate measurement of the spray drying characteristics, such as temperature and SO<sub>2</sub> concentration along the spray chamber, by varying the input and output variables. Tests were done to investigate the effects of spray characteristics, i.e., inlet gas phase temperature (120–180 ℃) and calcium-to-sulfur ratio (1–2.5), on SO<sub>2</sub> removal efficiency. The performance of the spray dryer was further evaluated based on the degree of conversion of calcium (sorbent utilization) after SO<sub>2</sub> absorption. Results indicated an increase in SO<sub>2</sub> removal efficiency by increasing the stoichiometric ratio and decreasing the temperature. Absorption efficiency of SO<sub>2</sub> beyond 90% was achieved at a stoichiometric ratio of 2.5. A high degree of conversion of calcium was realized at low stoichiometric ratios, with a maximum utilization of 94% obtained at a stoichiometric ratio of 1.5. The analysis of the final desulfurization product revealed the presence of sulfite with better conversion achieved at a stoichiometric molar ratio of 1.5. A significant amount of unreacted sorbent (63.43%) was observed at a stoichiometric ratio of 2, while samples collected at a stoichiometric ratio of 1.5 had the lowest concentration of unreacted Ca[OH]<sub>2</sub> (41.23%).</p> </abstract>