Abstract
Experimental evidence has been obtained for the structure-spectra relationship of hydrogen bonds in aqueous solutions. Intramolecular O-D distance, rOD, has been determined by the least-squares fitting analysis of the neutron interference term in the high-Q region observed for pure D2O and concentrated aqueous solutions. The average O-D stretching frequency, νOD, has been obtained from the position of the center of gravity of the observed ATR-IR O-D stretching band. The linear relationship between rOD and νOD has been confirmed in the liquid state. The slope of dνOD/drOD is evaluated to be -21 000 ± 1000 cm-1 Å-1.
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