Experimental determination and interpretation of fluorescence and fluorescence excitation spectra of 1,2-benzanthracene cooled in supersonic jet

Abstract

We measured the fluorescence and fluorescence excitation spectra of supersonic jet-cooled 1,2-benzanthracene. Using the MO/M8ST method, we calculated the frequencies of in-plane vibrations in the ground and first excited singlet electronic states, and, in the Franck-Condon approximation, we calculated the intensities of transitions between them. Experimental spectra are interpreted based on these data. In the fluorescence excitation spectrum, the position of the line of the 0–0 transition (26535 ± 1 cm−1), which is the most intense, is determined.