Abstract
Treatment of available electron paramagnetic resonance data of 2D ions of the 3d and 4d transition series taking into account the transfer of unpaired electronic density to the ligand molecules leads to experimental values of the core polarization within 20% of the theoretical estimates. Experimental values are given for Nb3+, Mo5+, Ag2+, VO2+, and Cu2+. Tentative values are also given for two 5d ions: Pt3+ and Re6+.
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