Experimental characterization of the Ne + ICl(X, ν″ = 0) and Ne + ICl(B, ν′ = 2) multi-dimensional intermolecular potentials

Abstract

Multiple features associated with transitions of the near T-shaped and linear Ne⋯I 35,37Cl(X, ν′ = 0) conformers are observed in laser-induced fluorescence spectra recorded in the ICl B–X, 2–0 and 3–0 spectral regions. The T-shaped complexes access the lowest intermolecular vibrational level, n b ′ = 0 , within the Ne + ICl(B, ν′) potential, while the linear complexes access four intermolecular bending levels, n b ′ = 1 – 4 , that form a progression of features up to the Ne + ICl(B, ν′) dissociation limit. The binding energy of the energetically more stable, ground state linear Ne⋯I 35Cl(X, ν″ = 0) conformer is measured to be 84(1) cm −1 in action spectroscopy experiments.