Experimental and theoretical temperature dependence of the rate coefficient of the B( 2P 1/2,3/2) + O 2(X 3Σ g−) reaction in the [24–295 K] temperature range

Abstract

The first study of the kinetics of B atoms with O 2 at low and ultra-low temperatures is reported. Rate constants have been measured from 295 down to 24 K using the pulsed-laser photolysis-laser-induced fluorescence technique in a Cinétique de Réaction en Ecoulement Supersonique Uniforme apparatus. Rate constants were found to increase monotonically with decreasing temperature. The temperature dependence of the rate constant has also been calculated using a theoretical approach based on the adiabatic capture centrifugal sudden approximation method. In the limit of zero temperature, the reactivities of the two spin orbit states of the B atom towards the O 2 molecule are also demonstrated to be different.