Experimental and numerical studies of NO reduction by ammonia in different methane flame positions

Abstract

Blending ammonia with methane for combustion can reduce carbon emissions and improve the flame characteristics of ammonia combustion. However, blending ammonia with methane can easily lead to high concentrations of NOx emissions. This study investigates the impact of different ammonia and methane blending methods on the flame structure and NOx emission by experiments and CFD numerical simulation. The results indicate that simultaneous injection of ammonia and methane through the central fuel tube significantly alters the combustion flame structure and leads to high concentrations of NOx emission. As the ammonia ratio increases, the flame structure transitions from a bright flame to a layered flame with an inner yellow conical small flame surrounded by a light-colored outer flame. When the ammonia ration increases from 0 % to 20 %, NOx emission increase from 15 ppm to 323 ppm, nearly 22 times higher. When ammonia is injected into the methane flame from flame side, the flame above the injection position appears as an orange flame, and a significant reduction in NOx emission is obtained. When the ammonia ratio is 20 % and injected at heights of 20 mm 40 mm, and 60 mm above the fuel exit, the outlet NOx concentrations are 183 ppm, 140 ppm, and 153 ppm respectively, this represents reductions of 43.3 %, 56.6 %, and 52.6 %, respectively. The numerical simulation results indicate that the injection of ammonia leads to the formation of higher concentrations of NH2 and super-vapor H2O, resulting in an orange color flame. The gas temperature and oxygen concentration play a crucial role in NOx emissions. NOx emission is lowest when ammonia is injected into the higher temperature, lower oxygen environment at 40 mm.