Experimental and numerical investigation of surface streamers in a nanosecond pulsed packed bed reactor

Abstract

Packed bed reactor (PBR) is the commonly used configuration in plasma catalysis, and its plasma characteristics have been extensively investigated. The filled catalysts in PBR make it challenging to carry out in-situ measurements of electric fields, and limited experimental data have been obtained. We investigated the surface streamer propagation and electric field distribution in a simplified PBR through simulations and experiments. The simplified PBR in the experiments is comprised of a blade-plate electrode structure filled with an Al2O3 column (ϵr = 9) in the discharge gap. An ICCD camera and an electric field diagnosis method called EFISH (electric field induced second harmonic generation) were employed, and a two-dimensional fluid model was established for the simulation. Four discharge types in the PBR were identified based on ICCD images and simulation results, including polar discharge at the contact areas, surface streamer along the dielectric column, expansion of surface discharge along the dielectric column, and surface ionization waves along the dielectric plate. Surface streamers with opposite propagation directions were found in the model, namely the forward streamer during the pulse rising time and the reverse streamer during the pulse falling time. Notably, the reverse streamer exhibits a significantly lower velocity compared to the forward streamer. Both experimental measurements and simulation were conducted to investigate the spatiotemporal electric field near the surface of the packing material. The results of both E exp and E sim showed peaks with opposite polarities, and exhibited similar trends. In the simulation, the forward streamer head showed a higher electric field compared to the reverse streamer head. Moreover, during the rest pulse time, the surface electric field was more intense at the contact areas than in other regions. The findings of this work provide valuable insights into the discharge mechanism and electric field on the catalytic material surface within the PBR.