Abstract

The primary aims of the QUENCH-18 bundle test were to examine the oxidation of M5® claddings in air/steam mixture following a limited pre-oxidation in steam, and to achieve a long period of oxygen and steam starvations to promote interaction with the nitrogen. Additionally, the QUENCH-18 experiment investigated the effects of the presence of two Ag-In-Cd control rods, and two pressurized unheated rod simulators (6 MPa, He). The twenty low-pressurized heater rods (0.23 MPa, similar to the system pressure) were Kr-filled. In a first transient, the bundle was heated in an atmosphere of flowing argon and superheated steam by electrical power increase to the peak cladding temperature of 1400 K. During this heat-up, claddings of the two pressurized rods were burst at temperature of 1045 K. The attainment of 1400 K marked the start of the pre-oxidation stage to achieve a maximum cladding oxide layer thickness of about 80 µm. In the air ingress stage, the steam and argon flows were reduced, and air was injected. The first Ag-In-Cd aerosol release was registered at 1350 K and was dominated by Cd bearing aerosols. Later in the transient, a significant release of Ag was observed. A strong temperature escalation started in the middle of the air ingress stage. During the air ingress stage, a period of oxygen starvation occurred, which was followed by almost complete steam consumption and partial consumption of the nitrogen indicating formation of zirconium nitrides under oxygen starvation conditions. The temperatures continued to increase and stabilized at the melting temperature of Zr bearing materials until water injection. Almost immediately after the start of reflood there was a temperature excursion, leading to maximum measured temperatures of about 2430 K. Final quench was achieved after about 800 s. A significant quantity of hydrogen was generated during the reflood (238 g). Nitrogen release (>54 g) due to re-oxidation of nitrides was also registered. Residual zirconium nitrides were observed in the bundle middle. The metallographic investigations of the bundle show strong cladding oxidation and Zr melt formation. The Zr melt relocated downwards to the lower bundle part was strongly oxidized. Partially oxidized Zr-bearing melt was found down to elevation 160 mm; this elevation was the lowest with evidence of relocated pellet material. At the bundle bottom, only frozen metallic melt containing Zr, Ag, In and Cd was observed between several rods. The experiment exhibited a multiplicity of phenomena for which the data will be invaluable for code assessment and for indicating the direction of model improvements. Example of code application with SCDAPSim is given at the end of this paper.

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