Experimental and Mechanistic Modeling of Fast Pyrolysis of Neat Glucose-Based Carbohydrates. 2. Validation and Evaluation of the Mechanistic Model

Abstract

A computational framework based on continuous distribution kinetics was constructed to solve the mechanistic model that was developed for fast pyrolysis of glucose-based carbohydrates in the first part of this study [Zhou et al. Ind. Eng. Chem. Res. 2014, 53. DOI 10.1021/ie502259w]. Comparing modeling results with experimental yields from fast pyrolysis over a wide range of reaction conditions validates the model. Agreement between model yields of final pyrolysis products with experimental data of fast pyrolysis of cellulose at temperatures ranging from 400 to 600 °C and maltohexaose, cellobiose, and glucose at 500 °C showed that the mechanistic model was robust and extendable. In comparison to our previous model [Vinu, R.; Broadbelt, L. J. Energy Environ. Sci. 2012, 5, 9808–9826], the mechanistic model presented in this work incorporating new findings from experiments and theoretical calculations showed enhanced performance in capturing experimental yields of major products such as levoglucosan-pyranose,...