Abstract
Producing tailor-made crystals demands knowledge of the influence of hydrodynamics and nucleation kinetics. In this paper, the hydrodynamic conditions in a dual-impeller crystallizer and their influence on the key nucleation parameters of the batch cooling crystallization of borax at different impeller off-bottom clearances were investigated. Two different impeller configurations were used—a dual pitched-blade turbine (2 PBT) and a dual straight-blade turbine (2 SBT). Hydrodynamics was analyzed in depth based on the developed computational fluid dynamics model. The experimental results on mixing time and power input were used to validate the numerical model. The results show that the properties of the final product are affected by the impeller position in both dual-impeller configurations. An increase in the impeller off-bottom clearance in both systems results in a decrease in the mean crystal size. The hydrodynamic conditions generated at C/D = 1 in the 2 PBT impeller system and at C/D = 0.6 in the 2 SBT impeller system favored an earlier onset of nucleation compared to other impeller positions. It was found that the eddy dissipation rate and the Kolmogorov length scale correlate highly with the mean crystal size, suggesting that the size is affected by the shear stress in the vessel, rather than the overall convective flow.
Published Version
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