Experimental analysis on calcination and carbonation process in calcium looping for CO2 capture: study case of cement plants in Indonesia

Abstract

AbstractCarbon dioxide (CO2) is the main contributor to greenhouse gases that affect global warming. The industrial sector is the third largest producer of CO2 and the cement industry is one of the industries that consistently produces the most significant CO2 emissions. The cement industry produces 5–8% of global CO2 emissions. Several methods for reducing specific CO2 emissions have been reported in the cement industry, including calcium looping, which uses the reversible reaction between calcination [calcium carbonate (CaCO3) decomposition] and carbonation [CO2 capture by calcium oxide (CaO)]. This work investigates calcium looping employing limestone obtained directly from several cement factories in Indonesia to observe the carbon-absorption characteristics of limestone from different mining locations. The experiment was carried out using a tube furnace equipped with a controlled atmospheric condition that functions as a calciner and a carbonator. X-ray diffraction and scanning electron microscopy with energy-dispersive x-ray spectroscopy characterization were conducted to analyse the changes in the experimental samples. The results demonstrated that the reactor configuration was capable of performing the calcination process, which converted CaCO3 to calcium hydroxide [Ca(OH)2], as well as the carbonation process, which captured carbon and converted it back to CaCO3. Parametric analysis was performed on both reactions, including pressure, temperature, duration, particle size and reaction atmosphere. The results show that the limestone obtained from all sites can be used as the sorbents for the calcium-looping process with an average reactivity of 59.01%. Limestone from cement plants in various parts of Indonesia has the potential to be used as carbon sorbents in calcium-looping technology. With a similar CO2 concentration as the flue gas of 16.67%, the experimental results show that Bayah limestone has the maximum reactivity, as shown by the highest carbon-content addition of 12.15 wt% and has the highest CO2-capture capability up to >75% per mole of Ca(OH)2 as a sorbent. Similar levels of the ability to capture CO2 per mole of Ca(OH)2 can be found in other limestones, ranging from 14.85% to 34.07%. The results show a promising performance of raw limestones from different mining sites, allowing further study and observation of the possibility of CO2 emission reduction in the sustainable cement-production process.