Abstract
The work presented here, demonstrates the on-board exhaust assisted catalytic ammonia (NH3) conversion to H2-N2 using either only exhaust heat (decomposition) or by direct reaction with part of the exhaust gas (reforming). The resultant H2-N2 gas mixture from the exhaust heat driven thermochemical energy recovery processes contains up to 15% more energy than the reactant NH3 (i.e. for 1 kW of NH3 used in the reaction up to 1.15 kW of H2 is produced). Experimental studies using a rhodium-platinum (Rh-Pt) catalyst and equilibrium calculations in Chemkin using Konnov’s 0.6 and Nozari’s reduced mechanisms have revealed that complete NH3 conversion occurs at typical gasoline direct injection (GDI) engine exhaust gas temperatures (450 °C–550 °C).By partially replacing gasoline in GDI engine with the resultant (H2-N2 products, up to 30% reduction in CO2 and fuels consumption can be achieved. Additional benefits can be gained under real engine operation when the benefits of reduced pumping losses, due to intake dilution with H2-N2 gas, are also considered. Furthermore, the work demonstrates additional benefits in CO2 life cycle for the NH3 use as an energy carrier in transportation and broader combustion power generation systems.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.