Excitonic polarons in low-dimensional transition metal dichalcogenides

Abstract

We examine the excitonic polaron properties of common monolayer transition metal dichalcogenides (MoS2, MoSe2, WS2 and WSe2). The excitonic polaron is formed when excitons interact with acoustic or optical phonons via coupling to the deformation potentials associated with the conduction and valence bands. A unitary transformation which performs an approximate diagonalization of the exciton–phonon operator is used to evaluate the ground state energy of the excitonic polaron. We derive analytical expressions of the changes in the excitonic polaron energy and mass at small exciton wavevectors involving the deformation potential due to optical phonons. The polaronic effect of the monolayer transition metal dichalcogenides is examined by comparing changes in the energy gap shift and effective masses based on known deformation potential constants for carrier–phonon interactions. Our results indicate the occurrence of comparable energy shifts when the ground state exciton interacts with optical or acoustic phonons. We extend our calculations to explore the influence of exciton–lattice interactions on the binding energies and the self-trapping of excitons in two-dimensional layers of transition metal dichalcogenides.